Natural Anthocyanins Based Dye Sensitized Solar Cell: A Review Paper
Corresponding Author(s) : Fatma B.Hamad
Journal of Humanities & Social Science (JHSS),
Vol. 5 No. 2 (2016)
Abstract
Anthocyanins are anthocyanidins (phenyl-2-benzopyrilium) coordinated with
glycosides at position 3 and/or 5. The carbonyl and hydroxyl groups of anthocyanin
molecules can be chemically bound on to the surface of semiconductors thereby
providing favourable condition for charge injection. Generally, bare wide band gap
semiconductors exhibit no absorption in the visible range. However, after
coordination with dye molecules, the absorption related to both transitions from
Valence Band (VB) to Conduction Band (CB) and from Highest Occupied Molecular
Orbital (HOMO) to Lowest Unoccupied Molecular Orbital (LUMO) are revealed
implying the sensitization of photoanode. Anthocyanins have proven to be among the
most versatile photosensitizers of wide band gap semiconductors in the Dye
Sensitized Solar Cells (DSSCs). This paper reviews the potential of anthocyanin
pigments from different sources as photosensitizers of wide band gap semiconductor
in DSSCs. The review focuses on the influence of different parameters such as the
nature of the dye and its preparation, type and morphology of photoelectrode, nature
of electrolyte, additives and co-absorbers on performance of DSSCs.
Keywords
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- BintiZulkifili, A., N. T. Kento, M. Daiki & A. Fujiki. 2015. The Basic Research on the Dye-Sensitized
- Solar Cells (DSSC). J. Clean Energy Technol., 3(5): 382–387.
- Brouillard, R. 1988. Flavonoids and Flower Colour. J. B. Harborne (ed.). In the Flavonoids. Advances
- in Research Since 1980. London: Chapman and Hall, p. 525.
- Buraidah, M. H., L. P. Teo, S. R. Majid, Yahya, R., R. M. Taha & A. K. Arof. 2010. Characterizations
- of Chitosan-Based Polymer Electrolyte Photovoltaic Cells. Int. J. Photoenergy, Volume 2010,
- Article ID 805836, 7 pages.
- Buraidah, M. H., L. P. Teo, S. N. F. Yusuf, M. M. Noor, , M. Z. Kufian, M. A. Careem, S. R. Majid, R.
- M. Taha & A. K. Arof. 2011. TiO2
- /Chitosan-NH4I(+I2)-BMII-Based Dye-Sensitized Solar Cells
- with Anthocyanin Dyes Extracted from Black Rice and Red Cabbage. Int. J. Photoenergy, Volume
- , Article ID 273683, 11 pages.
- Calogero, G., J. Yum, A. Sinopoli, G. Di Marco, M. Gratzel & M. Khaja Nazeeruddin,. 2012.
- Anthocyanins and Betalains as Light-harvesting Pigments for Dye-sensitized Solar Cells, Sol.
- Energy, 86: 1563–1575.
- Calogero, G., A. Bartolotta, G. Di Marco, A. Di Carlo & F. Bonaccorso. 2015. Vegetable-based DyeSensitized Solar Cells. Chem. Soc. Rev., 44: 3244–3294.
- Calogero, G. & G. Di Marco. 2008. Red Sicilian Orange and Purple Eggplant Fruits as Natural
- Sensitizers for Dye-sensitized Solar Cells. Sol. Energy Mat. Sol. Cells, 92: 1341–1346.
- Calzolari, A. 2015. Sensitization of ZnO Surface through Cyanidin Functionalization. J. SelfAssembly Mol. Electronic, 3: 1–12.
- Cherepy, N. J., G. P. Smestad, M. Gratzel & J. Z. Zhang. 1997. Ultrafast Electron Injection:
- Implications for a Photoelectrochemical Cell Utilizing an Anthocyanin Dye-Sensitized TiO2
- Nanocrystalline Electrode. J. Phys. Chem. B, 101: 9342–9351.
- Chien, C. & B. Hsu. 2013. Optimization of the Dye-sensitized Solar Cell with Anthocyanin as
- Photosensitizer. Sol. Energy, 98: 203–211.
- Dai, Q. & J. Rabani. 2001. Photosensitization of Nanocrystalline TiO2 Films by Pomegranate
- Pigments with Unusually High Efficiency in Aqueous Medium. Chem. Commun., 2142–2143,
- —. 2002a. Unusually Efficient Photosensitization of Nanocrystalline TiO2 Films by Pomegranate
- Pigments in Aqueous Medium. New J. Chem., 26: 421–426.
- —. 2002b. Photosensitization of Nanocrystalline TiO2 Films by Anthocyanin Dyes. J. Photochem.
- Photobiol. A, 148: 17–24.
- Delgado-Vargas, F., A. R. Jiménez & O. Paredes-López. 2000. Natural Pigments: Carotenoids,
- Anthocyanins & Betalains - Characteristics, Biosynthesis, Processing & Stability. Cri. Rev. Food
- Sci. Nutrition, 40(3): 173–289.
- Dumbrava, A., A. Georgescu, , G. Damache, , C. Badea, , I. Enache, C. Oprea & M. A. Gîrtu. 2008.
- Dye-sensitized Solar Cells Based on Nanocrystallinetio2 and Natural Pigments, J. Optoelectron.
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- with Aggregated Cyanine Dyes. J. Phys. Chem. B, 105: 9960–9965.
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- Energy. Inorg. Chem., 44, 6799–6801.
- El-Agez, T. M., A. A. El Tayyan, A. S. Al-Kahlout, A. Taya & M. S. Abdel-Latif. 2012. Dye-Sensitized
- Solar Cells Based on ZnO Films and Natural Dyes. Int. J. Mat. Chem. 2(3): 105–110.
- Fernando, J. M. R. C. & G. K. R. Senadeera,. 2008. Natural Anthocyanins as Photosensitizers for
- Dye-sensitized Solar Devices. Curr. Sci., 95: 663–664.
- Fossen, T., L. Cabrita & É. M. Andersen. 1998. Colour and Stability of Pure Anthocyanins
- Influenced by pH Including the Alkaline Region. Food Chem. 63(4): 435–440.
- Francis, F. J. 1989. Anthocyanins. Crit. Rev. Food Sci. Nutr. 28: 273–314.
- Furukawa, S., H. Iino, T. Iwamoto, K. Kukita & S. Yamauchi. 2009. Characteristics of DyeSensitized Solar Cells Using Natural Dye. Thin Solid Films, 518: 526–529.
- Garcia, C. G., A. S. Polo & N. Y. M. Iha. 2003. Fruit Extracts and Ruthenium Polypyridinic Dyes for
- Sensitization of TiO2
- in Photoelectrochemical Solar Cells. J. Photochem. Photobiol. A, 160: 87–91.
- Giusti, M. M., L. E. Rodri´guez-Saona & R. E. Wrolstad. 1999. Molar Absorptivity and Color
- Characteristics of Acylated and Non-AcylatedPelargonidin-Based Anthocyanins, J. Agric. Food
- Chem. 47: 4631-4637.
- Gokilamani, N., M. Thambidurai, T. S. Senthil, N. Muthukumarasamy, A. Ranjitha, D. Velauthapillai
- & R. Balasundaraprabhu. 2013. Dye-sensitized Solar Cells with Natural Dyes Extracted from
- Rose Petals. J. Mater Sci: Mater Electron, 24: 3394–3402.
- Grätzel, M. 2003. Dye-sensitized Solar Cells. J. Photochem. Photobiol. C., 4: 145–153.
- —. 2001. Photoelectrochemical Cells, Nature, 414: 338–344.
- Hao, S., J., Wu, Y. Huang & J. Lin. 2006. Natural Dyes as Photosensitizers for Dye-sensitized Solar
- Cell. Sol. Energy, 80: 209–214Harborne, J. B. 1988. The Flavonoids: Recent Advances. In T. W. Goodwin, (ed.). Plant Pigments.
- London: Academic Press, pp. 298–343.
- Hasoon, S. A., M.S. Raad, Al-Haddad, O. T. Shakir, I. M. Ibrahim. 2015. Natural Dye-Sensitized
- Solar Cell Based on Zinc Oxide. Int. J. Scient. Eng. Res., 6(5): 137–142.
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- Hoshino, T. 1991. An Approximate Estimate of Self-Association Constantsand the Self-stacking
- Conformation of Malvinquinonoidal Bases Studied by H NMR. Phytochem., 30: 2049–2055.
- Hug, H., M. Bader, P. Mair & T. Glatzel. 2014. Biophotovoltaics: Natural Pigments in Dye-sensitized
- Solar Cells. Appl. Energy. 115: 216–225.
- Jackman, R. L. & J. L. Smith. 1996. Anthocyanins and Betalains. In G. A. F. Hendry & J. D. Houghton
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References
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of Chitosan-Based Polymer Electrolyte Photovoltaic Cells. Int. J. Photoenergy, Volume 2010,
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with Anthocyanin Dyes Extracted from Black Rice and Red Cabbage. Int. J. Photoenergy, Volume
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Calogero, G., J. Yum, A. Sinopoli, G. Di Marco, M. Gratzel & M. Khaja Nazeeruddin,. 2012.
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Calogero, G., A. Bartolotta, G. Di Marco, A. Di Carlo & F. Bonaccorso. 2015. Vegetable-based DyeSensitized Solar Cells. Chem. Soc. Rev., 44: 3244–3294.
Calogero, G. & G. Di Marco. 2008. Red Sicilian Orange and Purple Eggplant Fruits as Natural
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Calzolari, A. 2015. Sensitization of ZnO Surface through Cyanidin Functionalization. J. SelfAssembly Mol. Electronic, 3: 1–12.
Cherepy, N. J., G. P. Smestad, M. Gratzel & J. Z. Zhang. 1997. Ultrafast Electron Injection:
Implications for a Photoelectrochemical Cell Utilizing an Anthocyanin Dye-Sensitized TiO2
Nanocrystalline Electrode. J. Phys. Chem. B, 101: 9342–9351.
Chien, C. & B. Hsu. 2013. Optimization of the Dye-sensitized Solar Cell with Anthocyanin as
Photosensitizer. Sol. Energy, 98: 203–211.
Dai, Q. & J. Rabani. 2001. Photosensitization of Nanocrystalline TiO2 Films by Pomegranate
Pigments with Unusually High Efficiency in Aqueous Medium. Chem. Commun., 2142–2143,
—. 2002a. Unusually Efficient Photosensitization of Nanocrystalline TiO2 Films by Pomegranate
Pigments in Aqueous Medium. New J. Chem., 26: 421–426.
—. 2002b. Photosensitization of Nanocrystalline TiO2 Films by Anthocyanin Dyes. J. Photochem.
Photobiol. A, 148: 17–24.
Delgado-Vargas, F., A. R. Jiménez & O. Paredes-López. 2000. Natural Pigments: Carotenoids,
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Dumbrava, A., A. Georgescu, , G. Damache, , C. Badea, , I. Enache, C. Oprea & M. A. Gîrtu. 2008.
Dye-sensitized Solar Cells Based on Nanocrystallinetio2 and Natural Pigments, J. Optoelectron.
Adv. Mat. 10(11): 2996–3002.
Ehret, A., L. Stuhl & M.T. Pitler,. 2001. Spectral Sensitization of TiO2 Nanocrytalline Electrodes
with Aggregated Cyanine Dyes. J. Phys. Chem. B, 105: 9960–9965.
Eisenberg, R. & D. G. Nocera. 2005. Preface: Overview of the Forum on Solar and Renewable
Energy. Inorg. Chem., 44, 6799–6801.
El-Agez, T. M., A. A. El Tayyan, A. S. Al-Kahlout, A. Taya & M. S. Abdel-Latif. 2012. Dye-Sensitized
Solar Cells Based on ZnO Films and Natural Dyes. Int. J. Mat. Chem. 2(3): 105–110.
Fernando, J. M. R. C. & G. K. R. Senadeera,. 2008. Natural Anthocyanins as Photosensitizers for
Dye-sensitized Solar Devices. Curr. Sci., 95: 663–664.
Fossen, T., L. Cabrita & É. M. Andersen. 1998. Colour and Stability of Pure Anthocyanins
Influenced by pH Including the Alkaline Region. Food Chem. 63(4): 435–440.
Francis, F. J. 1989. Anthocyanins. Crit. Rev. Food Sci. Nutr. 28: 273–314.
Furukawa, S., H. Iino, T. Iwamoto, K. Kukita & S. Yamauchi. 2009. Characteristics of DyeSensitized Solar Cells Using Natural Dye. Thin Solid Films, 518: 526–529.
Garcia, C. G., A. S. Polo & N. Y. M. Iha. 2003. Fruit Extracts and Ruthenium Polypyridinic Dyes for
Sensitization of TiO2
in Photoelectrochemical Solar Cells. J. Photochem. Photobiol. A, 160: 87–91.
Giusti, M. M., L. E. Rodri´guez-Saona & R. E. Wrolstad. 1999. Molar Absorptivity and Color
Characteristics of Acylated and Non-AcylatedPelargonidin-Based Anthocyanins, J. Agric. Food
Chem. 47: 4631-4637.
Gokilamani, N., M. Thambidurai, T. S. Senthil, N. Muthukumarasamy, A. Ranjitha, D. Velauthapillai
& R. Balasundaraprabhu. 2013. Dye-sensitized Solar Cells with Natural Dyes Extracted from
Rose Petals. J. Mater Sci: Mater Electron, 24: 3394–3402.
Grätzel, M. 2003. Dye-sensitized Solar Cells. J. Photochem. Photobiol. C., 4: 145–153.
—. 2001. Photoelectrochemical Cells, Nature, 414: 338–344.
Hao, S., J., Wu, Y. Huang & J. Lin. 2006. Natural Dyes as Photosensitizers for Dye-sensitized Solar
Cell. Sol. Energy, 80: 209–214Harborne, J. B. 1988. The Flavonoids: Recent Advances. In T. W. Goodwin, (ed.). Plant Pigments.
London: Academic Press, pp. 298–343.
Hasoon, S. A., M.S. Raad, Al-Haddad, O. T. Shakir, I. M. Ibrahim. 2015. Natural Dye-Sensitized
Solar Cell Based on Zinc Oxide. Int. J. Scient. Eng. Res., 6(5): 137–142.
Hernández-Martínez, A. R., M. Estevez, S. Vargas, F. Quintanilla & R. Rodríguez. 2012. Natural
Pigment-Based Dye-Sensitized Solar Cells. J. Appl. Res. Tech., 10(1): 38–47.
Horiuchi, T., H. Miura, K. Sumioka & S. Uchida. 2004. High Efficiency of Dye-sensitized Solar Cells
Based on Metal-free Indoline Dyes. J Am Chem Soc., 126: 12218–12219.
Hoshino, T. 1991. An Approximate Estimate of Self-Association Constantsand the Self-stacking
Conformation of Malvinquinonoidal Bases Studied by H NMR. Phytochem., 30: 2049–2055.
Hug, H., M. Bader, P. Mair & T. Glatzel. 2014. Biophotovoltaics: Natural Pigments in Dye-sensitized
Solar Cells. Appl. Energy. 115: 216–225.
Jackman, R. L. & J. L. Smith. 1996. Anthocyanins and Betalains. In G. A. F. Hendry & J. D. Houghton
(eds.), Natural Food Colorants, 2nd (ed.). Blackie A & P: Great Britain; Chapter 8.
Jackman, R. L., R. Y. Yada, M. A. Tung & R. A. Speers. 1987. Anthrocyanins as Food Colorants: A
Review. J. Food Biochem., 11: 201–247.
Jeong, H., Y. Lee, Y. Kim & M. Kang. 2010. Enhanced Photoelectric Efficiency by Surface Modification
of TiO2 Thin Film Using Various Acidic Species. Korean J. Chem. Eng. 27: 1462–1468.
Kelly, C. A. & G. J. Meyer. 2001. Excited State Processes at Sensitized Nanocrystalline Thin Film
Semiconductor Interfaces. Coord. Chem Rev., 211: 295–315.
Kim, H., Y. Bin, S. N. Karthick, K.V. Hemalatha, C. Justin Raj, S. Park & G. Vijayakumar, 2013.
Natural Dye Extracted from Rhododendron Species Flowers as a Photosensitizer in Dye
Sensitized Solar Cell. Int. J. Electrochem. Sci., 8: 6734–6743.
Liang Han, F. & Y. Xu. 2015. Effect of the Structure of Seven Anthocyanins on Self-association and
Colour in an Aqueous Alcohol Solution. S. Afr. J. Enol. Vitic., 36(1): 105–116.
Lapornik, B., M. Prosek & A. Golc Wondra. 2005. Comparison of Extracts Prepared from Plant Byproducts using Different Solvents and Extraction Time. J. Food Engineer, 71: 214–222.
Leydet, Y., R. Gavara, V. Petrov, A. M. Diniz, A. J. Parola, J. C. Lima & F. Pina. 2012. The Effect of
Self-aggregation on the Determination of the Kinetic and Thermodynamic Constants of the
Network of Chemical Reactions in 3-glucoside Anthocyanins. Phytochem. 83: 125–135.
Luo, P., H. Niu, G. Zheng, X. Bai, M. Zhang & W. Wang. 2009. From Salmon Pink to Blue Natural
Sensitizers for Solar Cells: Canna indicaL., Salvia Splendens, Cowberry and Solanumnigrum L.
Spectrochimica. Acta Part A, 74: 936–942.
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